I didn't see it mentioned here...the difference, as I understand it, is not that one grade is ANY better than another, but that the difference is the point at which each grade ignites under pressure. (http://engineering.mit.edu/ask/what%...gular-gasoline) if your engine isn't made for it, premium won't help it.
Finally, here's a link to a scholarly article search on the difference...I haven't checked out the articles but I'm sure they will be of great interest to those smarter than I.
http://scholar.google.com/scholar?hl...%2C33&as_sdtp=